Product Name: |
Natural 2-Heptanone |
Synonyms: |
2-Oxoheptane 1-Methylhexanal;2-Heptanone,98%;2-Heptanone,Methyl pentyl ketone;2-Heptanone, pure, 98%;2-Heptanone, 98%, pure;2-Heptanone, 98% 100ML;2-Heptanone, 98% 1LT;amyl-methyl-cetone(french) |
CAS: |
110-43-0 |
MF: |
C7H14O |
MW: |
114.19 |
EINECS: |
203-767-1 |
Product Categories: |
H;NMR Reference Standards;NMRStable Isotopes;Spectroscopy;Stable Isotopes;Carbon Steel Flex-Spout Cans;ACS and Reagent Grade Solvents;Amber Glass Bottles;Nutrition Research;Phytochemicals by Plant (Food/Spice/Herb);ReagentPlus;ReagentPlus Solvent Grade Products;Semi-Bulk Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Industrial/Fine Chemicals;G-HAlphabetic;HA -HTAnalytical Standards;Alphabetical Listings;Zingiber officinale (Ginger) |
Mol File: |
110-43-0.mol |
|
Melting point |
-35 °C |
Boiling point |
149 °C |
density |
0.82 |
vapor density |
3.94 (vs air) |
vapor pressure |
2.14 mm Hg ( 20 °C) |
FEMA |
2544 | 2-HEPTANONE |
refractive index |
n20/D 1.408(lit.) |
Fp |
106 °F |
storage temp. |
Flammables area |
solubility |
water: soluble4.21 g/L at 20°C |
form |
Liquid |
color |
Clear colorless |
explosive limit |
1.11-7.9%(V) |
Odor Threshold |
0.0068ppm |
Water Solubility |
4.3 g/L (20 ºC) |
JECFA Number |
283 |
Merck |
14,4663 |
BRN |
1699063 |
Henry's Law Constant |
3.59 at 37 °C (static headspace-GC, Bylaite et al., 2004) |
Exposure limits |
TLV-TWA 235 mg/m3 (50 ppm) (ACGIH), 465 mg/m3 (100 ppm) (NIOSH). . |
Stability: |
Stable. Flammable. Incompatible with strong oxidizing agents, strong reducing agents, strong bases. |
CAS DataBase Reference |
110-43-0(CAS DataBase Reference) |
NIST Chemistry Reference |
2-Heptanone(110-43-0) |
EPA Substance Registry System |
2-Heptanone (110-43-0) |
Hazard Codes |
Xn |
Risk Statements |
22-38-40-48/20/22-20/22-10 |
Safety Statements |
36-24/25 |
RIDADR |
UN 2810 6.1/PG 3 |
WGK Germany |
2 |
RTECS |
MJ5250000 |
Autoignition Temperature |
739 °F |
TSCA |
Yes |
HazardClass |
3 |
PackingGroup |
III |
HS Code |
29141990 |
Hazardous Substances Data |
110-43-0(Hazardous Substances Data) |
Toxicity |
LD50 orally in Rabbit: 1670 mg/kg LD50 dermal Rabbit 10332 mg/kg |
Description |
2-Heptanone has a characteristic banana, slightly spicy odor |
Chemical Properties |
2-Heptanone has a fruity, spicy, cinnamon, banana, slightly spicy odor. |
Chemical Properties |
colourless liquid |
Chemical Properties |
Methyl amyl ketone is a clear colorless liquid with a mild, banana-like odor. |
Physical properties |
Colorless liquid with a banana-like odor. Can be detected at a concentration of 140 μg/kg (Buttery et al., 1969a). Cometto-Mu?iz et al. (2000) reported nasal pungency threshold concentrations ranging from approximately 195 to 935 ppm. An odor threshold concentration of 6.8 ppbv was reported by Nagata and Takeuchi (1990). |
Occurrence |
Reported found in clove essential oil, Ceylon cinnamon and rancid coconut oil; also identifed in Ruta Montana Also reported found in banana, lingonberry, loganberry, black currant, guava, grapes, papaya, peach, pear, raspberry, other berries, strawberry jam, asparagus, roasted onion, leek, baked potato, mushroom, clove bud, ginger, blue, cheddar and Swiss cheeses, milk, cream, butter, fsh, meats, hop oil, beer, brandy, rum, malt whiskey, grape wines, cocoa, coffee, tea, peanuts, pecans, walnut, oats, soybeans, coconut oil, olive, passion fruit, mango, fgs, rice, sweet corn, corn tortillas, malt, caviar, shrimp, oysters, crab, crayfsh and mate |
Hazard |
Moderate fire risk. Toxic by inhalation, skin and eye irritant, narcotic in high concentration. |
Health Hazard |
Inhalation can cause headache, fatigue, nausea, vomiting, dizziness, stupor, drowsiness, disturbed vision, and unconsciousness. Skin contact can cause moderate irritation, defatting, and dermatitis. Ingestion may cause irritation of lips and mouth, gastro-intestinal irritation, nausea, diarrhea, drowsiness, loss of consciousness, weak and rapid pulse, cold-pale complexion. |
Health Hazard |
Exposure to methyl
amyl ketone causedirritation of mucous membranes, mild tomoderate congestion
of the lungs, and narcosis in test animals. A 4-hour exposure to a4000-ppm concentration
in air was lethal torats; 1500–2000 ppm produced lung irrita[1]tion and narcosis. The
concentration at whichit produces similar symptoms in humans isnot known. |
Fire Hazard |
Combustible liquid,
flash point (closed cup) 39.9°C (102°F), (open cup) 48.9°C (12°F); vapor
density 3.9 (air = 1) vapor pressure 2.6 torr at 20°C (68°F); autoignition
tempera[1]ture 393°C (740°F); fire-extinguishing
agent: “alcohol” foam; a water spray may be used to cool below its flash
point. |
Safety Profile |
Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin irritant. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also KETONES. |
Shipping |
UN1110 n-Amyl Methyl ketone, Hazard Class: 3; Labels: 3-Flammable liquid. |
Waste Disposal |
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. |