Natural 2-Heptanone
  • Natural 2-HeptanoneNatural 2-Heptanone

Natural 2-Heptanone

Natural 2-Heptanone's cas code is 110-43-0

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Product Description

Natural 2-Heptanone Basic information


Product Name:

Natural 2-Heptanone

Synonyms:

2-Oxoheptane 1-Methylhexanal;2-Heptanone,98%;2-Heptanone,Methyl pentyl ketone;2-Heptanone, pure, 98%;2-Heptanone, 98%, pure;2-Heptanone, 98% 100ML;2-Heptanone, 98% 1LT;amyl-methyl-cetone(french)

CAS:

110-43-0

MF:

C7H14O

MW:

114.19

EINECS:

203-767-1

Product Categories:

H;NMR Reference Standards;NMRStable Isotopes;Spectroscopy;Stable Isotopes;Carbon Steel Flex-Spout Cans;ACS and Reagent Grade Solvents;Amber Glass Bottles;Nutrition Research;Phytochemicals by Plant (Food/Spice/Herb);ReagentPlus;ReagentPlus Solvent Grade Products;Semi-Bulk Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Industrial/Fine Chemicals;G-HAlphabetic;HA -HTAnalytical Standards;Alphabetical Listings;Zingiber officinale (Ginger)

Mol File:

110-43-0.mol



Natural 2-Heptanone Chemical Properties


Melting point 

-35 °C

Boiling point 

149 °C

density 

0.82

vapor density 

3.94 (vs air)

vapor pressure 

2.14 mm Hg ( 20 °C)

FEMA 

2544 | 2-HEPTANONE

refractive index 

n20/D 1.408(lit.)

Fp 

106 °F

storage temp. 

Flammables area

solubility 

water: soluble4.21 g/L at 20°C

form 

Liquid

color 

Clear colorless

explosive limit

1.11-7.9%(V)

Odor Threshold

0.0068ppm

Water Solubility 

4.3 g/L (20 ºC)

JECFA Number

283

Merck 

14,4663

BRN 

1699063

Henry's Law Constant

3.59 at 37 °C (static headspace-GC, Bylaite et al., 2004)

Exposure limits

TLV-TWA 235 mg/m3 (50 ppm) (ACGIH), 465 mg/m3 (100 ppm) (NIOSH). .

Stability:

Stable. Flammable. Incompatible with strong oxidizing agents, strong reducing agents, strong bases.

CAS DataBase Reference

110-43-0(CAS DataBase Reference)

NIST Chemistry Reference

2-Heptanone(110-43-0)

EPA Substance Registry System

2-Heptanone (110-43-0)


Natural 2-Heptanone Safety Information


Hazard Codes 

Xn

Risk Statements 

22-38-40-48/20/22-20/22-10

Safety Statements 

36-24/25

RIDADR 

UN 2810 6.1/PG 3

WGK Germany 

2

RTECS 

MJ5250000

Autoignition Temperature

739 °F

TSCA 

Yes

HazardClass 

3

PackingGroup 

III

HS Code 

29141990

Hazardous Substances Data

110-43-0(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 1670 mg/kg LD50 dermal Rabbit 10332 mg/kg


Natural 2-Heptanone Usage


Description

2-Heptanone has a characteristic banana, slightly spicy odor

Chemical Properties

2-Heptanone has a fruity, spicy, cinnamon, banana, slightly spicy odor.

Chemical Properties

colourless liquid

Chemical Properties

Methyl amyl ketone is a clear colorless liquid with a mild, banana-like odor.

Physical properties

Colorless liquid with a banana-like odor. Can be detected at a concentration of 140 μg/kg (Buttery et al., 1969a). Cometto-Mu?iz et al. (2000) reported nasal pungency threshold concentrations ranging from approximately 195 to 935 ppm. An odor threshold concentration of 6.8 ppbv was reported by Nagata and Takeuchi (1990).

Occurrence

Reported found in clove essential oil, Ceylon cinnamon and rancid coconut oil; also identifed in Ruta Montana Also reported found in banana, lingonberry, loganberry, black currant, guava, grapes, papaya, peach, pear, raspberry, other berries, strawberry jam, asparagus, roasted onion, leek, baked potato, mushroom, clove bud, ginger, blue, cheddar and Swiss cheeses, milk, cream, butter, fsh, meats, hop oil, beer, brandy, rum, malt whiskey, grape wines, cocoa, coffee, tea, peanuts, pecans, walnut, oats, soybeans, coconut oil, olive, passion fruit, mango, fgs, rice, sweet corn, corn tortillas, malt, caviar, shrimp, oysters, crab, crayfsh and mate

Hazard

Moderate fire risk. Toxic by inhalation, skin and eye irritant, narcotic in high concentration.

Health Hazard

Inhalation can cause headache, fatigue, nausea, vomiting, dizziness, stupor, drowsiness, disturbed vision, and unconsciousness. Skin contact can cause moderate irritation, defatting, and dermatitis. Ingestion may cause irritation of lips and mouth, gastro-intestinal irritation, nausea, diarrhea, drowsiness, loss of consciousness, weak and rapid pulse, cold-pale complexion.

Health Hazard

Exposure to methyl amyl ketone causedirritation of mucous membranes, mild tomoderate congestion of the lungs, and narcosis in test animals. A 4-hour exposure to a4000-ppm concentration in air was lethal torats; 1500–2000 ppm produced lung irrita[1]tion and narcosis. The concentration at whichit produces similar symptoms in humans isnot known.
The oral toxicity of this compound is low.Its irritant action on skin should be low tovery low.
LD50 value, oral (mice): 730 mg/kg.

Fire Hazard

Combustible liquid, flash point (closed cup) 39.9°C (102°F), (open cup) 48.9°C (12°F); vapor density 3.9 (air = 1) vapor pressure 2.6 torr at 20°C (68°F); autoignition tempera[1]ture 393°C (740°F); fire-extinguishing agent: “alcohol” foam; a water spray may be used to cool below its flash point.
Methyl amyl ketone forms an explosive mixture with air in the range 1.1% [at 66°C (150.8°F)] to 7.9% [at 121°C (249.8°F)] by volume. It can react explosively with strong acids, alkalies, and oxidizing agents.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin irritant. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.

Shipping

UN1110 n-Amyl Methyl ketone, Hazard Class: 3; Labels: 3-Flammable liquid.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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