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Product Name: |
Leaf alcohol |
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CAS: |
928-96-1 |
|
MF: |
C6H12O |
|
MW: |
100.16 |
|
EINECS: |
213-192-8 |
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Mol File: |
928-96-1.mol |
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|
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Melting point |
22.55°C (estimate) |
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Boiling point |
156-157 °C(lit.) |
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density |
0.848 g/mL at 25 °C(lit.) |
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vapor density |
3.45 (vs air) |
|
refractive index |
n20/D 1.44(lit.) |
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FEMA |
2563 | CIS-3-HEXENOL |
|
Fp |
112 °F |
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storage temp. |
Flammables area |
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form |
Liquid |
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pka |
15.00±0.10(Predicted) |
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color |
APHA: ≤100 |
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Specific Gravity |
0.848 (20/4℃) |
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Water Solubility |
INSOLUBLE |
|
Merck |
14,4700 |
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JECFA Number |
315 |
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BRN |
1719712 |
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Stability: |
Stable. Substances to be avoided include strong oxidizing agents and strong acids. Flammable. |
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CAS DataBase Reference |
928-96-1(CAS DataBase Reference) |
|
NIST Chemistry Reference |
3-Hexen-1-ol, (Z)-(928-96-1) |
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EPA Substance Registry System |
(Z)-3-Hexen-1-ol (928-96-1) |
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Hazard Codes |
F |
|
Risk Statements |
10 |
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Safety Statements |
16 |
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RIDADR |
UN 1987 3/PG 3 |
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WGK Germany |
1 |
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RTECS |
MP8400000 |
|
F |
10 |
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TSCA |
Yes |
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HazardClass |
3 |
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PackingGroup |
III |
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HS Code |
29052990 |
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Description |
Leaf alcohol exists as a liquid at room temperature with a characteristic odor of green leaves. It is found in green tea, violet leaf oil, and many types of leaves, herbs, and grasses. Leaf alcohol finds applications in perfumery as floral fragrance. Leaf alcohol is also investigated for its antidiabetic activity. |
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Chemical Properties |
colourless liquid |
|
Chemical Properties |
Leaf Alcohol is a
colorless liquid with the characteristic odor of freshly cut grass. In small
quantities, leaf alcohol occurs in the green parts of nearly all plants. The
volatile flavor constituents of green tea contain up to 30%. |
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Chemical Properties |
cis-3-Hexen-l-ol has an intense, green odor, not as strong as the corresponding aldehyde and a characteristic herbaceous, leafy odor on dilution. This substance can be obtained through extraction from various essential oils and purified by reacting it to the corresponding phthalate or allophanate; it was synthesized by Ruzicka and Schinz, who also clarified its chemical structure; Stoll and Rouve reported on the most significant differences between the natural and the synthetic products. |
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Chemical Properties |
3-Hexen-1-ol has an intense, grassy-green odor, not as strong as the corresponding aldehyde, and a characteristic her[1]baceous, leafy odor on dilution. |
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Definition |
ChEBI: A primary alcohol that consists of (3Z)-hex-3-ene substituted by a hydroxy group at position 1. |
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Aroma threshold values |
Detection: 70 ppb |
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Taste threshold values |
Taste characteristics at 30 ppm: fresh, green, raw fruity with a pungent depth |
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Chemical Synthesis |
Extracted from various essential oils and purified by reacting it to the corresponding phthalate or allophanate; it was synthesized by Ruzi-ka and Schinz, who also clarified its chemical structure; Stoll and Rouve reported on the most significant differ[1]ences between the natural and the synthetic products (Burdock, 1995) |
|
References |
[1] NPCS Board of
Consultants & Engineers, Industrial Alcohol of Technology Handbook, 2010 |
|
Preparation Products |
CIS-3-HEXENYL BUTYRATE-->FEMA 3498-->TRANS,CIS-2,6-NONADIEN-1-OL-->cis-3-Hexenyl formate-->cis-3-Hexenai-->cis-3-Hexenyl 2-methylbutanoate-->1-HEXEN-3-YL ACETATE-->cfs-3-trans-2-Hexenyl propionate(mixtme) |
|
Raw materials |
Sodium-->Ammonia-->Triphenylphosphine-->Litium-->SODIUM ACETYLIDE-->3-HEXYNE-->1-HEXYN-3-OL-->1-BUTYNE |
